Chapter 4
Compounds in natural environments (air, oceans, rocks, soils, living systems)
14
Ionic compounds found in nature (salts & minerals)
5 subtopics
15
Sea-salt ions and evaporite salts (natural brines and oceans)
3 subtopics
16
NaCl — sodium chloride (halite; common salt)
17
MgCl2 — magnesium chloride (found in seawater/brines)
18
KCl — potassium chloride (sylvite; evaporite mineral)
19
Carbonate minerals and buffering salts
2 subtopics
20
CaCO3 — calcium carbonate (calcite/limestone/chalk)
21
NaHCO3 — sodium hydrogen carbonate (sodium bicarbonate; nahcolite in nature)
22
Sulfate minerals (common ionic solids in rocks/soils)
2 subtopics
23
CaSO4·2H2O — calcium sulfate dihydrate (gypsum)
24
MgSO4·7H2O — magnesium sulfate heptahydrate (epsomite)
25
Soil nutrient salts (naturally occurring ions important to ecosystems)
2 subtopics
26
KNO3 — potassium nitrate (niter/saltpeter; natural deposits)
27
NH4NO3 — ammonium nitrate (occurs naturally; also widely manufactured)
28
Natural metal sulfides/oxides (ore minerals; largely ionic/extended solids)
2 subtopics
29
FeS2 — iron disulfide (pyrite; “fool’s gold”)
30
Fe2O3 — iron(III) oxide (hematite; common iron ore)
31
Covalent compounds found in nature (molecules & network covalent solids)
4 subtopics
32
Water and small atmospheric/biogenic molecules
4 subtopics
34
CO2 — carbon dioxide (a major atmospheric and dissolved gas)
35
CH4 — methane (natural gas; produced by wetlands and microbes)
36
NH3 — ammonia (biogenic nitrogen compound; also industrially important)
37
Natural organics and biomolecule examples (covalent)
4 subtopics
38
C6H12O6 — glucose (a monosaccharide)
39
(C6H10O5)n — cellulose (a polysaccharide biopolymer)
40
C2H6O — ethanol (fermentation product; natural + engineered)
41
C6H8O7 — 2-hydroxypropane-1,2,3-tricarboxylic acid (citric acid)
42
Network covalent solids in nature
2 subtopics
43
SiO2 — silicon dioxide (silica/quartz; network covalent)
44
C — carbon (diamond; network covalent allotrope)
45
Naturally occurring acids in waters and biochemistry
2 subtopics
46
H2CO3 — carbonic acid (formed from dissolved CO2 in water)
47
CH3COOH — ethanoic acid (acetic acid; produced biologically)
48
Linking natural observations: map carbon/nitrogen/sulfur species across air–water–soil